Roeland - to be clear, what frame is this? B5? C5? Continental GT?
This is a standard 500cc 2012 C5 with a ported head, factory piston?
What is the measured cranking compression?
I believe that the electric start has a decompressor mechanism built in. If the cams aren't stock, this feature is likely gone.
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https://accessories.hitchcocksmotorcycles.com/20040qty=1&continue_url=https%3A%2F%2Fwww.hitchcocksmotorcycles.com%2Fpartsbook-pages%2F4985 )
PART No. 570309 ; CAM GEAR ASSEMBLY-EXHAUST WITH DECOMPRESSOR ASSEMBLY ; £147.79
As far as I know from this forum, people install a "button" decompressor or Bullet decompressor unit in the head if that function is desired. I don't see a "exhaust valve lifter" unit offered for other than the Bullet.
What kind of knobbies are these tyres, trials universals? Motard? If you are on the street at more than maybe 65 MPH on trials universals you're rolling the dice.
Wheel alignment is checked with a string, front to back, on the centerstand. You are verifying that the front & rear tyre contact patches are absolutely in line, not offset. Spokes can be tuned to move the rim a bit, otherwise it's machine work & spacers. The rear sprocket needs to stay centered on the front sprocket while you are doing this as well.
When you oversized the rear tyre you reduced fork rake geometry. More rake generally translates to stability, less for turning ability. All of this interacts in complex ways.
I would put S (112 MPH) or H (130 MPH) rated street tires of the OEM size back on it. The cams should go back to stock, then you should be able to use the e-start. These are 27-30 HP machines, it takes about 35 HP to "reliably" run 100+ MPH, rider blended into the paint. Then you'd have something you could ride. If it easily runs freeway speeds, that's good enough. That ACE head will buy you some there!
If you want to go fast, it's too easy to acquire a 600 class 80 HP+ Japanese asphalt scratcher that'll run 130+ for $2500 - $4000, less than the cost of any hop up you could ever do to the Enfield, and safer too. You are buying race-proven geometry & suspension and a current-tech motor that will move it down the road at terrifying velocities. I've even seen a few rideable Hayabusas & ZX12's for under $5000 with their 170+ top end speeds. Enjoy a
rideable Enfield, leave real speed to the "clean sheet of paper" designs. Or get a Royal Enfield 650 Interceptor or Continental, they'll broach the "ton" right out of the box and don't weigh much more than the singles.